Santosh Kumar, S. C. and Manjunatha, J. R. and Srinivas, P. and Bettadaiah, B. K. (2014) Eco-friendly kinetic separation of trans-limonene and carvomenthene oxides. Journal of Chemical Sciences, 126 (3). pp. 875-880.
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Abstract
Kinetic separation of trans-limonene oxide and trans-carvomenthene oxide was achieved in high
yield by selective ring opening of their cis-epoxides in the presence of InCl3 catalyst in water. Catalytic activity
of InCl3 was conserved up to 10 cycles. Nucleophilic addition of methanol in presence of InCl3 was also selective
as cis-epoxides preferentially reacted leaving behind trans-epoxides, which were separated by fractional
distillation.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Eco-friendly kinetic separation indium chloride cis-/trans-limonene oxide cis-/trans-carvomenthene oxide water |
| Subjects: | 500 Natural Sciences and Mathematics > 04 Chemistry and Allied Sciences > 24 Organic Chemistry |
| Divisions: | Plantation Products Spices and Flavour Technology |
| Depositing User: | Food Sci. & Technol. Information Services |
| Date Deposited: | 14 Oct 2014 05:40 |
| Last Modified: | 16 Jan 2017 12:33 |
| URI: | http://ir.cftri.res.in/id/eprint/11645 |
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