Rao, J. M. and Nair, P. M. (1970) Structure and mutarotation of ascorbic acid osazones. Tetrahedron, 26. pp. 3833-3838.
Tetrahedron Vol 26. pp. 3833 to 3838.pdf - Published Version
Restricted to Registered users only
Download (487kB) | Request a copy
Abstract
study of ascorbic acid osazones by spectroscopic methods shows that they are y-lactones,
not Mactones as claimed recently. It is found that they mutarotate in solution. Mutarotation involves
geometric isomerization of the hydrazone moieties and replacement of one chelate system by another. The
path for isomerization is discussed.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | ascorbic acid, osazones, spectrosocopic methods |
| Subjects: | 500 Natural Sciences and Mathematics > 04 Chemistry and Allied Sciences > 24 Organic Chemistry |
| Divisions: | Plantation Products Spices and Flavour Technology |
| Depositing User: | Food Sci. & Technol. Information Services |
| Date Deposited: | 05 Mar 2018 08:25 |
| Last Modified: | 05 Mar 2018 08:25 |
| URI: | http://ir.cftri.res.in/id/eprint/5534 |
