Modelling solubility of phenolics of mango ginger extract in supercritical carbon dioxide using equation of state and empirical models.
Krishna Murthy, T. P. and Manohar, B. (2015) Modelling solubility of phenolics of mango ginger extract in supercritical carbon dioxide using equation of state and empirical models. Journal of Food Science and Technology, 52 (9). pp. 5557-5567. ISSN 0022-1155
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Journal of Food Science and Technology September 2015, Volume 52, Issue 9, pp 5557-5567.pdf - Published Version Restricted to Registered users only Download (353kB) |
Abstract
Solubility of phenolics of mango ginger extract in supercritical carbon dioxide was studied at 40– 60 °C and 100–350 bar. Critical temperature, critical pressure and critical volume of caffeic acid, the principal component of the extract were calculated using group contribution methods and compared with the values obtained by CHEMDRAW®. Vapor pressure of caffeic acid was predicted by Reidel method. Solubility prediction in supercritical carbon dioxide was studied using two different equation of states (EOS) models and eight empirical models. Peng-Robinson EOS predicted the solubility very well with average deviation of 0.68 % from the experimental solubility. Empirical equations based on the simple error minimization using non-linear regression method which do not require complex physiochemical properties was also found suitable to predict the solubility at different extraction conditions. Jouyban et al. model showed very less deviation (2.25 %) for predicted solubility values from the experiment.
Item Type: | Article |
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Uncontrolled Keywords: | Mango ginger . Solubility . Supercritical CO2 . Equation of state . Empirical models |
Subjects: | 600 Technology > 08 Food technology > 01 Analysis 600 Technology > 08 Food technology > 30 Spices/Condiments |
Divisions: | Food Engineering |
Depositing User: | Food Sci. & Technol. Information Services |
Date Deposited: | 29 Dec 2015 07:04 |
Last Modified: | 29 Dec 2015 07:04 |
URI: | http://ir.cftri.res.in/id/eprint/12039 |
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