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Microwave-Assisted Synthesis Of Alkyl Thiocyanates.

James Bound, D. and Bettadaiah, B. K. and Srinivas, P. (2013) Microwave-Assisted Synthesis Of Alkyl Thiocyanates. Synthetic Communications, 43. pp. 1138-1144.

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Microwave irradiation accelerated the reaction of t-alkyl, allyl, and benzyl halides with Zn(SCN)2 to afford thiocyanates in excellent yields and high selectivity with the formation of isothiocyanates only in minor proportions. Because thiocyanates are stable intermediates to thiols, the method also affords facile access to corresponding thiols.

Item Type: Article
Uncontrolled Keywords: Allyl; benzyl; halides; isothiocyanates; microwave; selectivity; t-alkyl; thiocyanates; zinc thiocyanate
Subjects: 600 Technology > 08 Food technology > 15 Flavour/Fragrance/Perfumes
600 Technology > 08 Food technology > 06 Preservation and Storage > 04 Irradiation
Divisions: Plantation Products Spices and Flavour Technology
Depositing User: Food Sci. & Technol. Information Services
Date Deposited: 26 Apr 2013 09:08
Last Modified: 12 Jun 2019 08:46
URI: http://ir.cftri.res.in/id/eprint/11202

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