James Bound, D. and Bettadaiah, B. K. and Srinivas, P. (2013) Microwave-Assisted Synthesis Of Alkyl Thiocyanates. Synthetic Communications, 43. pp. 1138-1144.
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Abstract
Microwave irradiation accelerated the reaction of t-alkyl, allyl, and benzyl halides
with Zn(SCN)2 to afford thiocyanates in excellent yields and high selectivity with the
formation of isothiocyanates only in minor proportions. Because thiocyanates are stable
intermediates to thiols, the method also affords facile access to corresponding thiols.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Allyl; benzyl; halides; isothiocyanates; microwave; selectivity; t-alkyl; thiocyanates; zinc thiocyanate |
| Subjects: | 600 Technology > 08 Food technology > 15 Flavour/Fragrance/Perfumes 600 Technology > 08 Food technology > 06 Preservation and Storage > 04 Irradiation |
| Divisions: | Plantation Products Spices and Flavour Technology |
| Depositing User: | Food Sci. & Technol. Information Services |
| Date Deposited: | 26 Apr 2013 09:08 |
| Last Modified: | 12 Jun 2019 08:46 |
| URI: | http://ir.cftri.res.in/id/eprint/11202 |
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